Mechanistic Studies on the Mukaiyama Epoxidation
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چکیده
منابع مشابه
Mechanistic studies on the Mukaiyama epoxidation.
A detailed mechanistic study on the Mukaiyama epoxidation of limonene with dioxygen as oxidant, bis(acetylacetonato)nickel(II) as catalyst, and an aldehyde as co-reagent is reported. All major products of the reaction have been quantitatively identified, both with isobutyraldehyde and 2-methylundecanal as co-reacting aldehydes. Limonene epoxide is formed in good yield. The main products evolvin...
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ژورنال
عنوان ژورنال: The Journal of Organic Chemistry
سال: 2004
ISSN: 0022-3263,1520-6904
DOI: 10.1021/jo030345a